Jennifer Aniston says her “chemistry” with Paul Rudd has “always been there”.

The Hollywood pair have maintained a good working relationship over the years, appearing in films including The Object of My Affection and more recently Wanderlust.

Both actors have a great on-screen chemistry, which Jennifer admits is very natural.

“I just think it’s something that has been there. I mean, it’s grown – because we’ve grown, but I think that that chemistry has always been there,” she told Access Hollywood.

Jennifer and Paul engage in a few semi-naked scenes in the comedy film, including one with a prosthetic penis.

Jennifer says the experience was a totally new one for her.

“That’s a first – that’s an absolute first,” Jennifer insisted before Paul pondered about the question. “That’s not your first?” Jennifer laughed.

Wanderlust is produced by famed comedy director Judd Apatow and tells the story of a married Manhattan couple who move to a rural commune after facing sudden unemployment. The film also stars Jennifer’s partner Justin Theroux.

The actress says the relaxed script allowed for the cast to improvise throughout.

“There would be the scene as written, then there would be a Judd Apatow touch where he would have these alternate lines written, so we would try version one, version two, version three. They were all hilarious, I don’t know how they decided what to put together,” Jennifer said.

“Then there were also times when we would keep rolling and see what happened,” Paul added.

The pair admit that the final edit was made appropriate for the big screen.

“There was so much that was naughty that got cut,” Jennifer exclaimed before Paul laughed: “There is only so much disgusting stuff the audience is gonna handle!”

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Jennifer Aniston proud of Rudd chemistry