What lies beneath growing islands of graphene is important to its properties, according to a new study led by Rice University. Scientists at Rice analyzed patterns of graphene - a single-atom-thick sheet of carbon - grown in a furnace via chemical vapor deposition. They discovered that the geometric relationship between graphene and the substrate, the underlying material on which carbon assembles atom by atom, determines how the island shapes emerge.

The study led by Rice theoretical physicist Boris Yakobson and postdoctoral researcher Vasilii Artyukhov shows how the crystalline arrangement of atoms in substrates commonly used in graphene growth, such as nickel or copper, controls how islands form. The results appeared in Physical Review Letters.

"Experiments that show graphene's amazing electronic properties are typically done on mechanically exfoliated graphene," Artyukhov said.

"That limits you in terms of the flake size, and it's expensive if you need a lot of material. So everybody's trying to come up with a better way to grow it from gases like methane (the source of carbon atoms) using different substrate metals. The problem is, the resulting crystals look different from substrate to substrate, even though it's all graphene."

Yakobson said researchers often see odd-shaped graphene islands grown by chemical vapor deposition, "and we have all wondered why. In general, this is very surprising, because in graphene, the six sides should be identical." Triangles and other shapes, he said, are examples of symmetry breaking; systems that would otherwise produce regular shapes "break" and produce less regular ones.

Graphene forms in a chemical vapor deposition furnace when carbon atoms floating in the hot fog settle on the metallic substrate. The atoms link up in characteristic six-sided rings, but as an island grows, its overall shape can take various forms, from hexagons to elongated hexagons to more random structures, even triangles.

The researchers found a strong correlation between the ultimate shape of the island and the arrangement of atoms in the exposed surface of the substrate, which can be triangular, square, rectangular or otherwise.

The researchers found individual atoms follow the road map set out by the substrate, as illustrated by a microscope image of two grains of copper substrate that host two distinct shapes of graphene, even though the growth conditions are identical. On one grain, the graphene islands are all nearly perfect hexagons; on the other, the hexagonal islands are elongated and aligned.

"The image shows the basic growth mechanisms are the same, but the difference in the islands is due to the subtle differences between the crystallographic surfaces of the graphene and copper," Yakobson said.

Because graphene's edges are so important to its electronic properties, any step toward understanding its growth is important, he said. Whether a graphene edge ends up as a zigzag, an armchair or something in between depends on how individual atoms fall into equilibrium as they balance energies between their neighboring carbon atoms and those of the substrate.

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Symmetry matters in graphene growth