Since World War I, the vast majority of American combat casualties has come not from gunshot wounds but from explosions. Today, most soldiers wear a heavy, bullet-proof vest to protect their torso but much of their body remains exposed to the indiscriminate aim of explosive fragments and shrapnel.

Designing equipment to protect extremities against the extreme temperatures and deadly projectiles that accompany an explosion has been difficult because of a fundamental property of materials. Materials that are strong enough to protect against ballistic threats cant protect against extreme temperatures and vice versa. As a result, much of todays protective equipment is composed of multiple layers of different materials, leading to bulky, heavy gear that, if worn on the arms and legs, would severely limit a soldiers mobility.

Now, Harvard University researchers, in collaboration with the U.S. Army Combat Capabilities Development Command Soldier Center (CCDC SC) and the United States Military Academy at West Point, have developed a lightweight, multifunctional nanofiber material that can protect wearers from both extreme temperatures and ballistic threats.

The research is published in the journal Matter.

"When I was in combat in Afghanistan, I saw firsthand how body armor could save lives, said senior author Kit Parker, the Tarr Family Professor of Bioengineering and Applied Physics at the Harvard John A. Paulson School of Engineering and Applied Sciences (SEAS) and a lieutenant colonel in the United States Army Reserve. I also saw how heavy body armor could limit mobility. As soldiers on the battlefield, the three primary tasks are to move, shoot, and communicate. If you limit one of those, you decrease survivability and you endanger mission success."

Our goal was to design a multifunctional material that could protect someone working in an extreme environment, such as an astronaut, firefighter or soldier, from the many different threats they face, said Grant M. Gonzalez, a postdoctoral fellow at SEAS and first author of the paper.

In order to achieve this practical goal, the researchers needed to explore the tradeoff between mechanical protection and thermal insulation, properties rooted in a materials molecular structure and orientation.

Materials with strong mechanical protection, such as metals and ceramics, have a highly ordered and aligned molecular structure. This structure allows them to withstand and distribute the energy of a direct blow. Insulating materials, on the other hand, have a much less ordered structure, which prevents the transmission of heat through the material.

Kevlar and Twaron are commercial products used extensively in protective equipment and can provide either ballistic or thermal protection, depending on how they are manufactured. Woven Kevlar, for example, has a highly aligned crystalline structure and is used in protective bulletproof vests. Porous Kevlar aerogels, on the other hand, have been shown to have high thermal insulation.

Our idea was to use this Kevlar polymer to combine the woven, ordered structure of fibers with the porosity of aerogels to make long, continuous fibers with porous spacing in between, said Gonzalez. In this system, the long fibers could resist a mechanical impact while the pores would limit heat diffusion.

The research team used immersion Rotary Jet-Spinning (iRJS), a technique developed by Parkers Disease Biophysics Group, to manufacture the fibers. In this technique, a liquid polymer solution is loaded into a reservoir and pushed out through a tiny opening by centrifugal force as the device spins. When the polymer solution shoots out of the reservoir, it first passes through an area of open air, where the polymers elongate and the chains align. Then the solution hits a liquid bath that removes the solvent and precipitates the polymers to form solid fibers. Since the bath is also spinning like water in a salad spinner the nanofibers follow the stream of the vortex and wrap around a rotating collector at the base of the device.

By tuning the viscosity of the liquid polymer solution, the researchers were able to spin long, aligned nanofibers into porous sheets providing enough order to protect against projectiles but enough disorder to protect against heat. In about 10 minutes, the team could spin sheets about 10 by 30 centimeters in size.

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Multifunctional nanofiber protects against extreme temperatures and fast-moving projectiles - Harvard School of Engineering and Applied Sciences